Simple flow-injection system for the simultaneous determination of nitrite and nitrate in water samples*1

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Simple flow-injection system for the simultaneous determination of nitrite and nitrate in water samples.

A novel spectrophotometric reaction system was developed for the determination of nitrite as well as nitrate in water samples, and was applied to a flow-injection analysis (FIA). The spectrophotometric flow-injection system coupled with a copperised cadmium reductor column was proposed. The detection was based on the nitrosation reaction between nitrite ion and phloroglucinol (1,3,5-trihydroxyb...

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Spectrophotometric simultaneous determination of nitrite, nitrate and ammonium in soils by flow injection analysis.

A new rapid flow injection procedure for the simultaneous determination of nitrate, nitrite and ammonium in single flow injection analysis system is proposed. The procedure combines on-line reduction of nitrate to nitrite and oxidation of ammonium to nitrite with spectrophotometric detection of nitrite by using the Griess-Ilosvay reaction. The formed azo dye was measured at 543 nm. The influenc...

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Simultaneous spectrophotometric determination of nitrite and nitrate by flow-injection analysis.

An automatic direct spectrophotometric method for the simultaneous determination of nitrite and nitrate by flow-injection analysis has been developed. Nitrite reacts with 3-nitroaniline in the presence of hydrochloric acid (0.96-1.8 M HCl or pH 0.5-0.7) to form a diazonium cation, which is subsequently coupled with N-(1-naphthyl)-ethylenediamine dihydrochloride to form a stable purple azo dye, ...

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simulation and experimental studies for prediction mineral scale formation in oil field during mixing of injection and formation water

abstract: mineral scaling in oil and gas production equipment is one of the most important problem that occurs while water injection and it has been recognized to be a major operational problem. the incompatibility between injected and formation waters may result in inorganic scale precipitation in the equipment and reservoir and then reduction of oil production rate and water injection rate. ...

Simple Flow Injection Analysis System for the Spectrophotometric Determination of Trace Amounts of Nitrite in Water Samples

A simple and sensitive spectrophotometric flow injection analysis system has been developed for the determination of trace amounts of nitrite. The method is based on the reaction of nitrite with sulfanilamide in acidic medium to form a diazonium salt which then couples with thenoyltrifluoroacetone in alkaline medium to give an azo dye. Beer’s law is obeyed at 470 nm over a nitrite concentration...

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ژورنال

عنوان ژورنال: Talanta

سال: 2004

ISSN: 0039-9140

DOI: 10.1016/j.talanta.2004.03.059